It is true that a white-FM process (or whatever units we are actually using for the waveform that allantools is expecting to be fractional frequency versus time) would go down at a rate of 1/root-tau consistent with averaging a white noise process over N samples with the standard deviation going down at the square-root of N. Note that the samples to the far right on the Allan Deviation have the biggest error confidence bar intervals since they have the lowest number of samples in their own solution, so can be least trusted in their own accuracy. However with sufficient samples we can still get this behaviour where the ADEV goes down faster than rate 1/root-tau when the spectrum of the noise process itself is not white and specifically the noise closer to the carrier is lower than the noise further away. Examples where this can occur would be the noise spectrum out of sigma-delta converters where the upper portion of the spectrum past the noise shaping corner can indeed be white, but below the noise shaping corner the noise rolls off rapidly. For that we would see a behavior consistent with the OP's plot of having noise going down at 1/root-tau up to a certain tau, and then dropping off faster than that consistent with the noise shaping slope.
Below is an example of such a sigma-delta spectrum where we could see this in the ADEV.
