Taken from Guide to DSP where it says:
... at two ... standard deviations from the mean, the value of the Gaussian curve has dropped to about 1/19 ...
It seems to be a straight forward calculation but my math just didn't work out to 1/19. The Gaussian probability distribution function is given by:
$$ P(x) = {1 \over \sqrt{2\pi} \sigma } e^{-{{(x - \mu)^2} \over {2 \sigma^2}}} $$
At the mean (where maximum probability occurs),
$$ \begin{align} P(\mu) &= {1 \over \sqrt{2\pi} \sigma } e^{-{{(\mu - \mu)^2} \over {2 \sigma^2}}} \\ &= {1 \over \sqrt{2\pi} \sigma } e^{0} = {1 \over \sqrt{2\pi} \sigma} \end{align} $$
And at 2 standard deviation, or $ x = \mu +2\sigma $
$$ \begin{align} P(\mu + 2\sigma) &= {1 \over \sqrt{2\pi} \sigma } e^{-{{(\mu + 2\sigma - \mu)^2} \over {2 \sigma^2}}} \\ &= {1 \over \sqrt{2\pi} \sigma } e^{-{{4\sigma^2} \over {2 \sigma^2}}} = {1 \over \sqrt{2\pi} \sigma } e^{-2} \end{align} $$
To see how much probability has dropped from max probability at $ \mu $ to probability at $ 2\sigma $, I can simply take the ratio:
$$ { P(\mu + 2 \sigma) \over P(\mu) } = { {{1 \over {\sqrt{2\pi}\sigma}} e^{-2}} \over {{1 \over {\sqrt{2\pi}\sigma}}}} = e^{-2} = 0.135 \approx {2 \over 15} \neq {1 \over 19} $$