Consider N-point sequence $x[n]$ whose N-point DFT is $X[k]$. To compute 2N-point DFT, $X_2[k]$, of $x[n]$, one should append N-zeroes to $x[n]$, and make it a 2N-point sequence, denoted $x_2[n]$. Obviously, first N-samples of $x[n]$ and $x_2[n]$ are identical, and last N-samples of $x_2[n]$ are just zeroes.
Write 2N-point DFT of $x_2[n]$:
$$ X_2[k] = \sum_{n=0}^{2N-1} x_2[n] e^{-j \frac{2 \pi}{2N} n k } ~~,~~ k=0,1,...,2N-1 \tag{1}$$
which is identical to:
$$ X_2[k] = \sum_{n=0}^{N-1} x[n] e^{-j \frac{2 \pi}{N} n (k/2) } ~~,~~ k=0,1,...,2N-1 \tag{2}$$
Now, the even indexed samples of $X_2[k]$ can be shown to be $X[k/2]$, by setting $k_e=2m$ in Eq.2, $m=0,1,...,N-1$ :
$$ X_2[2m] = \sum_{n=0}^{N-1} x[n] e^{-j \frac{2 \pi}{N} n (2m/2) } = X[m] \tag{3}$$
The odd indexed samples of $X_2[k]$ can also be obtained similarly by setting $k_o = 2m+1$, in Eq.2:
$$ X_2[2m+1] = \sum_{n=0}^{N-1} x[n] e^{-j \frac{2 \pi}{N} n (\frac{2m+1}{2}) } = X[m+0.5] \tag{4}$$
Eq.4 is an interpolation statement; i.e., the sample $X[m+0.5]$ implies (but does not perform) interpolation between $X[m]$ and $X[m+1]$. However, it's not proper to set $k=m+0.5$ into the argument of a sequence, which is a mathematical array of numbers indexed by an integer; fractional indices make no literal sense. Nevertheless, Eq.4 means that taking 2N-point DFT of an N-point sequence, effectively, interpolates between samples of N-point DFT of the N-point sequence.
On the other hand, one can manipulate Eq.4 to see that:
$$ X_2[2m+1] = \sum_{n=0}^{N-1} x[n] e^{-j \frac{2 \pi}{N} n (\frac{2m+1}{2}) } = X[m+0.5] \tag{5}$$
$$ X_2[2m+1] = \sum_{n=0}^{N-1} x[n] e^{-j \frac{ \pi}{N} n} e^{-j \frac{2 \pi}{N} n m } \tag{6}$$
denoting $x_o[n] = x[n] e^{-j \frac{ \pi}{N} n}$ yields
$$ X_2[2m+1] = \sum_{n=0}^{N-1} x_o[n] e^{-j \frac{2 \pi}{N} n m} = X_o[m]\tag{7}$$
Where $X_o[m]$ is the N-point DFT of the sequence $x_o[n]$. Time-domain modulation of $x[n]$ by $ e^{-j \frac{ \pi}{N} n}$, performs half-sample shift of its N-point DFT $X[k]$, thus describe the so called interpolated values $X[k+0.5]$.