The sequence is exactly what you should expect:
$$x[-n]=x[N-n]\tag{1}$$
Clearly, for $n=0$ $x[n]$ and $x[-n]$ have the same value.
It seems like you were expecting to see the sequence $x[N-1-n]$ instead of $x[N-n]$. If you wanted that sequence you would need to modulate the result of the first DFT:
N = 16;
x = 1:N;
c = exp(-1i*2*pi/N*(0:N-1));
x2 = real( fft( ( fft(x) .* c ) ) ) / N; % real() just to remove rounding errors
x2 =
16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1